Don't forget to close rundll32.exe process in Task Manager after finishing playing. Now try to launch the game again, it must work. Close toy2.exe but don't touch rundll32.exe (it's a Windows app for running old apps from 32-bit operational systems, most old games running through rundll32.exe).
Also try to launch the game, then open Task Manager (Ctrl+Alt+Del by default) and check for processes toy2.exe and rundll32.exe.Right click on toy2.exe - Properties - Compatibility - Set 'Run this app in compatibility mode with Windows 95/98, Windows 2000 or Windows XP'. If the game doesn't run - open the directory with the game and find toy2.exe. After you installed the game, install Toy Story 2 Fix (simply extract all files to the game directory).Also it is recommended to install DirectX from the disc (inside the disc image in 'Setup' - 'DirectX' folder).You will need the utility for mounting disc image files, like WinCDEmu, UltraISO, Alcohol 52%/Alcohol 102% or Daemon Tools Lite